nach oben

Erschienen in:

16.12.2022 | Original

Effect of deep eutectic solvent pretreatment on defibrillation efficiency and characteristics of lignocellulose nanofibril

verfasst von: Chan-Woo Park, Jaegyoung Gwon, Song-Yi Han, Ji-Soo Park, Rajkumar Bandi, Ramakrishna Dadigala, Jeong-Ki Kim, Gu-Joong Kwon, Seung-Hwan Lee

Erschienen in: Wood Science and Technology | Ausgabe 1/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this study, a deep eutectic solvent (DES) pretreatment using choline chloride (ChCl)/lactic acid (LA), betaine (BE)/LA, and potassium carbonate (PC)/glycerol (GLY) was used to prepare lignocellulose nanofibrils (LCNF). An increase in the reaction temperature (100, 120, and 130 °C) and time (6, 12, and 24 h) caused a decrease in the content of lignin and hemicellulose in lignocellulose (Pinus densiflora S. et Z.). Lignocellulose nanofibrils (LCNFs) were prepared from the DES-treated products using a high-pressure homogenizer. As the lignin content of the DES-treated products decreased, the defibrillation efficiency of the LCNFs improved, resulting in a smaller diameter, longer filtration time, larger specific surface area, higher water retention value, and higher viscosity. DES pretreatment using ChCl/LA was more effective for delignification and improvement of defibrillation efficiency than pretreatment using BE/LA and PC/GLY. A decrease in the lignin content caused an increase in the crystallinity index and crystallite size. The significant delignification due to the ChCl/LA treatment can be attributed to the improved tensile properties of the LCNF nanosheets.

Vorheriger Artikel Birch wood biorefinery into microcrystalline, microfibrillated, and nanocrystalline celluloses, xylose, and adsorbents

Nächster Artikel Untargeted metabolomics analysis of Diospyros celebica Bakh. from three different geographical origins in Sulawesi island using UHPLC-Q-Orbitrap HRMS

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Abbott AP, Capper G, Davies DL, Rasheed RK, Tambyrajah V (2003) Novel solvent properties of choline chloride/urea mixtures. Chem Commun (camb) 1(1):70–71. https://doi.org/10.1039/b210714gCrossRef

Abe K, Yano H (2012) Cellulose nanofiber-based hydrogels with high mechanical strength. Cellulose 19(6):1907–1912. https://doi.org/10.1007/s10570-012-9784-3CrossRef

Alvarez-Vasco C, Ma R, Quintero M, Guo M, Geleynse S, Ramasamy KK, Wolcott M, Zhang X (2016) Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents (DES): a source of lignin for valorization. Green Chem 18(19):5133–5141. https://doi.org/10.1039/C6GC01007ECrossRef

Baati R, Mabrouk AB, Magnin A, Boufi S (2018) CNFs from twin screw extrusion and high pressure homogenization: a comparative study. Carbohydr Polym 195:321–328. https://doi.org/10.1016/j.carbpol.2018.04.104CrossRefPubMed

Chen Z, Wan C (2018) Ultrafast fractionation of lignocellulosic biomass by microwave-assisted deep eutectic solvent pretreatment. Bioresour Technol 250:532–537. https://doi.org/10.1016/j.biortech.2017.11.066CrossRefPubMed

Chen W, Yu H, Liu Y, Chen P, Zhang M, Hai Y (2011) Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments. Carbohydr Polym 83(4):1804–1811. https://doi.org/10.1016/j.carbpol.2010.10.040CrossRef

Chen Z, Bai X, Wan C (2018) High-solid lignocellulose processing enabled by natural deep eutectic solvent for lignin extraction and industrially relevant production of renewable chemicals. ACS Sustain Chem Eng 6(9):12205–12216CrossRef

Chun SJ, Lee SY, Doh GH, Lee S, Kim JH (2011) Preparation of ultrastrength nanopapers using cellulose nanofibrils. J Ind Eng Chem 17(3):521–526. https://doi.org/10.1016/j.jiec.2010.10.022CrossRef

Francisco M, van den Bruinhorst A, Kroon MC (2012) New natural and renewable low transition temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing. Green Chem 14(8):2153–2157. https://doi.org/10.1039/c2gc35660kCrossRef

Galland S, Berthold F, Prakobna K, Berglund LA (2015) Holocellulose nanofibers of high molar mass and small diameter for high-strength nanopaper. Biomacromol 16(8):2427–2435. https://doi.org/10.1021/acs.biomac.5b00678CrossRef

Huang C, Dong H, Zhang Z, Bian H, Yong Q (2020) Procuring the nano-scale lignin in prehydrolyzate as ingredient to prepare cellulose nanofibril composite film with multiple functions. Cellulose 27(16):9355–9370. https://doi.org/10.1007/s10570-020-03427-9CrossRef

Kumar AK, Parikh BS, Pravakar M (2016) Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue. Environ Sci Pollut Res Int 23(10):9265–9275. https://doi.org/10.1007/s11356-015-4780-4CrossRefPubMed

Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose–Its barrier properties and applications in cellulosic materials: a review. Carbohydr Polym 90(2):735–764. https://doi.org/10.1016/j.carbpol.2012.05.026CrossRefPubMed

Lee SH, Chang F, Inoue S, Endo T (2010) Increase in enzyme accessibility by generation of nanospace in cell wall supramolecular structure. Bioresour Technol 101(19):7218–7223. https://doi.org/10.1016/j.biortech.2010.04.069CrossRefPubMed

Lin W, Xing S, Jin Y, Lu X, Huang C, Yong Q (2020) Insight into understanding the performance of deep eutectic solvent pretreatment on improving enzymatic digestibility of bamboo residues. Bioresour Technol 306:123163. https://doi.org/10.1016/j.biortech.2020.123163CrossRefPubMed

Ling Z, Guo Z, Huang C, Yao L, Xu F (2020) Deconstruction of oriented crystalline cellulose by novel levulinic acid based deep eutectic solvents pretreatment for improved enzymatic accessibility. Bioresour Technol 305:123025. https://doi.org/10.1016/j.biortech.2020.123025CrossRefPubMed

Liu Y, Guo B, Xia Q, Meng J, Chen W, Liu S, Wang Q, Liu Y, Li J, Yu H (2017) Efficient cleavage of strong hydrogen bonds in cotton by deep eutectic solvents and facile fabrication of cellulose nanocrystals in high yields. ACS Sustain Chem Eng 5(9):7623–7631. https://doi.org/10.1021/acssuschemeng.7b00954CrossRef

Loow YL, New EK, Yang GH, Ang LY, Foo LYW, Wu TY (2017) Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion. Cellulose 24(9):3591–3618. https://doi.org/10.1007/s10570-017-1358-yCrossRef

Loow YL, Wu TY, Yang GH, Ang LY, New EK, Siow LF, Md Jahim JM, Mohammad AW, Teoh WH (2018) Deep eutectic solvent and inorganic salt pretreatment of lignocellulosic biomass for improving xylose recovery. Bioresour Technol 249:818–825. https://doi.org/10.1016/j.biortech.2017.07.165CrossRefPubMed

Lynam JG, Kumar N, Wong MJ (2017) Deep eutectic solvents’ ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density. Bioresour Technol 238:684–689. https://doi.org/10.1016/j.biortech.2017.04.079CrossRefPubMed

Nobuta K, Teramura H, Ito H, Hongo C, Kawaguchi H, Ogino C, Kondo A, Nishino T (2016) Characterization of cellulose nanofiber sheets from different refining processes. Cellulose 23(1):403–414. https://doi.org/10.1007/s10570-015-0792-yCrossRef

Park CW, Han SY, Choi SK, Lee SH (2017a) Preparation and properties of holocellulose nanofibrils with different hemicellulose content. BioResources 12(3):6298–6308. https://doi.org/10.15376/biores.12.3.6298-6308CrossRef

Park CW, Han SY, Namgung HW, Seo PN, Lee SY, Lee SH (2017b) Preparation and characterization of cellulose nanofibrils with varying chemical compositions. BioResources 12(3):5031–5044. https://doi.org/10.15376/biores.12.3.5031-5044CrossRef

Procentese A, Raganati F, Olivieri G, Russo ME, Rehmann L, Marzocchella A (2018) Deep eutectic solvents pretreatment of agro-industrial food waste. Biotechnol Biofuels 11(1):37. https://doi.org/10.1186/s13068-018-1034-yCrossRefPubMedPubMedCentral

Sirviö JA, Visanko M, Liimatainen H (2015) Deep eutectic solvent system based on choline chloride-urea as a pre-treatment for nanofibrillation of wood cellulose. Green Chem 17(6):3401–3406. https://doi.org/10.1039/C5GC00398ACrossRef

Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications. Chem Rev 114(21):11060–11082. https://doi.org/10.1021/cr300162pCrossRefPubMed

Trovagunta R, Zou T, Österberg M, Kelley SS, Lavoine N (2021) Design strategies, properties and applications of cellulose nanomaterials-enhanced products with residual, technical or nanoscale lignin – A review. Carbohydr Polym 254:117480. https://doi.org/10.1016/j.carbpol.2020.117480CrossRefPubMed

van Osch DJ, Kollau LJ, van den Bruinhorst A, Asikainen S, Rocha MA, Kroon MC (2017) Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation. Phys Chem Chem Phys 19(4):2636–2665. https://doi.org/10.1039/c6cp07499eCrossRefPubMed

Wang H, Li J, Zeng X, Tang X, Sun Y, Lei T, Lin L (2020) Extraction of cellulose nanocrystals using a recyclable deep eutectic solvent. Cellulose 27(3):1301–1314. https://doi.org/10.1007/s10570-019-02867-2CrossRef

Xia Q, Liu Y, Meng J, Cheng W, Chen W, Liu S, Liu Y, Li J, Yu H (2018) Multiple hydrogen bond coordination in three-constituent deep eutectic solvents enhances lignin fractionation from biomass. Green Chem 20(12):2711–2721. https://doi.org/10.1039/C8GC00900GCrossRef

Zhang L, Tsuzuki T, Wang X (2015) Preparation of cellulose nanofiber from softwood pulp by ball milling. Cellulose 22(3):1729–1741. https://doi.org/10.1007/s10570-015-0582-6CrossRef

Zulkefli S, Abdulmalek E, Abdul Rahman MBA (2017) Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk. Renew Energy 107:36–41. https://doi.org/10.1016/j.renene.2017.01.037CrossRef

Titel: Effect of deep eutectic solvent pretreatment on defibrillation efficiency and characteristics of lignocellulose nanofibril
verfasst von: Chan-Woo Park
Jaegyoung Gwon
Song-Yi Han
Ji-Soo Park
Rajkumar Bandi
Ramakrishna Dadigala
Jeong-Ki Kim
Gu-Joong Kwon
Seung-Hwan Lee
Publikationsdatum: 16.12.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Wood Science and Technology / Ausgabe 1/2023
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI: https://doi.org/10.1007/s00226-022-01444-4

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2023

Micromechanical analytical and inverse numerical modeling methods for determining the transverse elastic modulus of bamboo

Editorial

A comprehensive evaluation of axial gas permeability in wood using XCT imaging

Birch wood biorefinery into microcrystalline, microfibrillated, and nanocrystalline celluloses, xylose, and adsorbents

Variation of shear creep properties of wood within a stem: effects of macro- and microstructural variability

Image-based microstructural simulation of thermal conductivity for highly porous wood fiber insulation boards