Evaluation of wet tensile shear strength and surface properties of finger-jointed acetylated beech (Fagus sylvatica L.) laminated veneer lumber

The industrial modification facility of ACCOYA^® in Arnhem, the Netherlands, was used to acetylate rotary-cut beech (Fagus sylvatica L.) veneers (2200 × 1000 mm²), while half of the veneers were kept as untreated references. Using five samples that were picked at random, ACCOYA^® calculated the weight percent gain (WPG) of the acetylated veneers to be approximately 24.4% (SD 0.5%). Afterwards eight-layered LVL boards were manufactured in a hot press (HP-S 1200, Gottfried Joos Maschinenfabrik GmbH & Co. KG) using a two component phenol formaldehyde resin (Bakelite PF 128, 200 g/m²) at 145 °C. A similar sample set before bonding had a moisture content (MC) of 2.97% (SD 0.26%, n = 50) for the acetylated samples and 8.69% (SD 0.40%, n = 50) for the references (Slabohm et al. 2022b). Lamellas (200 × 100 × 19 mm³) were cut out of the manufactured boards.

A finger-jointing line (Type Ultra TT, Weinig Grecon GmbH & Co. KG, Alfeld/Leine, Germany) was used to vertically cut the finger-jointing profile of the conditioned (20 °C and 65% relative humidity (RH)) lamellas (200 × 100 mm²) with a cutting feed rate of 17 m/min. For each material-adhesive combination, seven lamellas were produced. The finger pitch was 6.2 mm, and the finger length was 20.75 mm. Three commercially available adhesives (MUF, 280 g/m²; phenol resorcinol formaldehyde (PRF), 380 g/m²; one-component polyurethane (PUR), 140 g/m²) were applied on the freshly cut surfaces. As advised by the supplier, the MUF and PUR were applied manually one-sided whereas the PRF was applied two-sided. After the initial application, the open assembly time did not exceed 120 s, and the closed assembly time was set to 30 s (SD 2 s). Reduced specific pressure (13 N/mm²) for 5 s was applied to avoid longitudinal cracking of the small cross-sections (100 × 19 mm²) of the acetylated lamellas. The bonded lamellas were stored for several weeks at 20 °C and 65% RH to ensure curing.

Finger-jointed lamellas (≈360 × 100 × 19 mm³) were cut once more at both end faces (Fig. 1). The milled finger-joints were sawn off and utilized as described below for CA (a) and roughness measurements (b). The lamella was then planned to 10 mm in thickness and sliced lengthwise in three 25 mm broad stripes. After that, a 150 mm long sample of each lamella was cut out with the finger-joints precisely in the middle (c). One of the two remaining specimens (d) was utilized to estimate the sample density and MC.

The MC and density were immediately determined after cutting the specimens (d, Fig. 1). First, specimens were stored at 20 °C and 65% RH to determine the conditioned MC (MC_cond.) and thereafter, the same specimens were exposed to four hours boiling in water, 18 h drying at 60 °C, again four hours boiling in water and two hours of cooling in water at room temperature to determine the water-soaked MC (MC_wet). Both MC were calculated according to the following Eq. (1).where m_dry = oven-dry mass (g), m_wet = wet mass (g)

In total, the tensile shear strength (TSS) of 126 specimens was tested (21 for each material-adhesive combination). Tests were carried out on the testing equipment Zwick/Roell (Ulm, Germany) with a maximum load cell of 10 kN and the textXpert^® III V3.5 (Zwick/Roell, Ulm, Germany) software. Using a digital microscope (VHX-5000, Keyence, Osaka, Japan), the bondline length was determined twice on each sample before exposure to water. Specimens had the size of 150 × 25 × 10 mm³ (c, Fig. 1). Before testing, all specimen were exposed to four hours boiling in water, 18 h drying at 60 °C, four hours boiling in water, and additional two hours cooling in water at room temperature. Specimens were tested in wet stage. The wet tensile shear strength (TSS) was calculated according to the following Eq. (2). Figure 2 depicts the test configuration.where F_max = maximum load [N], A = area of bonded finger-joints [mm²], a = length of bondline (excluding tip gap) [mm], b = specimen thickness [mm]

A laser-scanning-microscope (LSM) (VK-X110, control unit: VK-X100, equipped with a red laser (658 nm) Keyence, Osaka, Japan) was used to measure the surface roughness on five finger-joints (b, Fig. 1) for each lamella within four hours after cutting. Specimens were scanned with 10 × magnification (2043 × 1536 px) and a resolution of 0.434 µm. A field of 1350 × 1012 µm² was scanned and scans were merged afterwards (1 × 5). An automatic, linear inclination correction of the entire image was performed as an F-operation using the program VK-H1XAD, module ISO 25178 (Keyence Corporation, Osaka, Japan). The surface's long-wavelength components were eliminated by using a double Gaussian filter (based on EN ISO 16610-1 2015). Numerous roughness parameters were calculated (based on EN ISO 25178-1 2016) using the software VK-H1XAD, module ISO 25178 (Keyence Corporation, Osaka, Japan).

Contact angle (CA) measurements were conducted on five finger-joints (a, Fig. 1) per lamella within four hours after cutting using the Mobile Surface Analyzer Flexible Liquid (Krüss GmbH, Hamburg, Germany) with drop shape function Fitmethod Ellipse (Tang.-1). Adhesives were dropped manually and CA was automatically determined by the software ADVANCE (Krüss GmbH, Hamburg, Germany). Five measurements at intervals of one second were performed for each of the five finger-joints.

Statistical computing and graphics were made using the software R (RStudio Team 2022). To illustrate the distribution of the data set boxplots were used. One-way analyses of variance (ANOVA) were used to compare the effect of modification on MC_cond., MC_wet, and surface parameters. Two-way ANOVA was conducted to compare the effect of adhesive and modification on TSS and CA.

The oven-dry density of acetylated LVL was higher compared to untreated references (Table 1). Similar oven-dry densities were also found in similar studies for acetylated beech LVL (Slabohm et al. 2022b) and acetylated beech (Čermák et al. 2022). This can be explained by the added weight from bound acetyl groups that result during acetylation with acetic anhydride. For example, in this study approximately 24.4% WPG were achieved. Nevertheless, there are other factors that cause density to decrease during acetylation. The veneer expands, for instance in a tangential direction, as a result of cell wall bulking, which reduces the density of the acetylated material. Untreated beech LVL densifies more during the hot-bonding process than acetylated LVL (Slabohm et al. 2022b), which increases the density of the untreated specimen.

In the wet stage, acetylated and untreated specimens had almost the same density. For acetylated specimens, water uptake may be primarily in the cell lumen and very little in the cell wall, while untreated specimens absorb more water into the cell wall (see also next section).

Minor changes in density compared to other studies (Slabohm et al. 2022b) may be caused by a number of circumstances, such as (1) variable adhesive concentrations and different adhesives as well as (2) a potential reduction in densification due to shorter pressing times, various pressures and larger boards (upscaling effect), for instance. Additionally, there are already significant variations in the density of solid beech wood (Bouriaud et al. 2004; Gryc et al. 2008; Zeller et al. 2017).

Figure 3 provides important information on the MC_cond and MC_wet of acetylated and untreated LVL. The MC_cond. and MC_wet are certainly lower on acetylated specimens compared to references. For acetylated (beech) wood, reduced MC_cond. is regularly noted (Čermák et al. 2022; Militz 1991; Slabohm and Militz 2022a, b). Blocking of hygroscopic –OH groups and bulked cell walls are the main causes of the lower MC_cond. (Hill 2006). The reason why the MC_wet of acetylated specimen still increases after immersion in water is mainly due to water in the lumen, and that very little water is soaked in the cell wall (Hill 2006).

Bonding with the MUF showed lowest wet TSS of all three applied adhesives and acetylated specimens showed even lower performance compared to references (Fig. 4). First of all, MUF adhesives are recognized to have a low water resistance (Frihart 2005, pp. 255–257). According to the same source, MUF can be viewed as a compromise between low cost of UF adhesives, which are not water resistant, and higher water resistance of MF adhesives. Additionally, it is well known that using MUF adhesives to bond acetylated wood results in poor performance (Bongers et al. 2016; Lütkemeier et al. 2018; Treu et al. 2020). The lowered TSS might be due to a changed curing reaction, which is a result of the changed chemistry on acetylated specimens. For example, small amounts of remaining acetic acid might impact the (surface) pH and buffering capacity (Bongers and Uphill 2019). On the other hand, Olaniran et al. (2021) discovered that MUF-bonded acetylated rubberwood (Hevea brasiliensis, Müll. Arg.) had a reasonably high wet TSS. By applying a resorcinol–formaldehyde (RF) resin as a primer, Treu et al. (2020) enhanced the bonding with MUF. They found out that RF decreased the CA, indicating a more wettable surface. Yet resorcinol is highly costly. Lütkemeier et al. (2018) used a different strategy and sanded the surface (P100), which increased the TSS in both dry and wet settings and the percentage of wood failure in dry state.

The best bonding performance was achieved when specimens were bonded with the PRF for both acetylated and untreated. On acetylated wood, PRF resins are recognized for achieving strong bonding (Slabohm and Militz 2022b; Vick and Rowell 1990). For illustration, the traffic bridge in Sneek, the Netherlands, which is built with acetylated wood, was bonded using this adhesive type (Jorissen and Luning 2010; Tjeerdsma and Bongers 2009). It is also known that phenol and resorcinol create strong, water-resistant bonds (Frihart 2005, pp. 250–254). According to the same author, much like MUF adhesive is a compromise of MF and UF, PRF resins are a compromise of phenol and resorcinol in order to lower costs and maintain the benefit of resorcinol's ability to cure at room temperature.

The 1-C PUR adhesive exhibited comparably high TSS as the specimens bonded with the PRF. This is in line with other studies, which showed the effective bonding with PUR on acetylated wood (Bongers et al. 2016; Lütkemeier et al. 2018). However, it was anticipated that the bonding with PUR could exhibit poor bonding performance since the MC_cond. before bonding (Fig. 3) is reduced and water is required for the curing of PUR (Lehringer and Gabriel 2014). It is much likely that the low MC before bonding and the surrounding RH during the open assembly period provided already sufficient water for the curing. Additionally, during storage (after bonding) at 20 °C and 65% RH, curing of the adhesive might have taken place. Even if the TSS is already quite high, applying a primer prior to the 1-C PUR adhesive can improve the bonding performance of hardwoods such as beech (Luedtke et al. 2015).

Figure 4 also displays a decreased TSS of PRF and PUR bonded LVL for untreated LVL in comparison to acetylated specimen. According to Hofferber et al. (2006), swelling and shrinking cause stresses on the bonding, which might lower the TSS of the bonding. Additionally, mechanical properties of untreated wood generally decrease with increasing MC until the fiber saturation point (Niemz and Sonderegger 2017). For example, the TSS of acetylated LVL marginally dropped after a boiling-drying-boiling cycle compared to dry state TSS, whereas that of untreated LVL drastically decreased following boiling in water (Slabohm and Militz 2022a). After acetylation, any sorbed water is primarily in the lumen rather than in the cell wall (see also section above). Therefore, water has a minimal impact on the mechanical properties after acetylation on wood. However, one should be aware that there are further decreasing and increasing factors on the mechanical properties during acetylation (Beckers and Bongers 2003; Bongers et al. 2016; Laine et al. 2016; Militz 1991).

Figure 5 displays typical finger-joint failure modes. In this study, specimen broke mainly entirely inside the bonded area (A, Fig. 5). It was less than ideal that the maximum load of 10 kN of the test machine was achieved in a few cases during the testing of most of the acetylated PRF specimens (D, Fig. 5). However, the result still demonstrates that of the three adhesives, PRF performed the best.

The wood failure percentage (WF) was assessed in addition to the TSS. However, it was too difficult to determine accurately the WF on such tiny pieces. Results on WF are therefore not presented. Because there is no standard for investigating the WF of finger-joints, other standards may be adapted (for example EN 314-1 2005).

Two randomly chosen three-dimensional sample topographies (untreated and acetylated) are shown in Fig. 6. The topography on other images may appear differently.

The topography of acetylated finger-joints appears to have only minor differences compared to untreated LVL (Fig. 7). Significantly different was the arithmetical mean surface height (Sa), which indicates a smoother surface on acetylated finger-joints. This is in line with another study (Lütkemeier 2018). Other roughness parameters as maximum height (Sz), developed interfacial area ratio (Sdr), and texture aspect ratio (Str) were similar on acetylated LVL and references. The negative skewness (Ssk) indicated a topographic deviation to the higher side for both materials, which is typical for porous materials like wood (Sandak et al. 2021). Sharpness (Sku) was greater than three, indicating a higher leptokurtic distribution rather than a normal distribution for both materials.

The CA for MUF and PRF was slightly lower on acetylated specimens compared to references and almost the same for PUR (Fig. 8). This result was somewhat unexpected, because many studies showed a hydrophobic behavior after acetylation (Ayoub et al. 2013; Bryne and Wålinder 2010; Chi et al. 2008; Wålinder et al. 2013). The main reasons for this hydrophilic behavior are the replacement of hydroxyls by the relatively hydrophobic ester groups, blocked pathways due to bulking and more stable extractives (Wålinder et al. 2013). However, often water and other liquids were used to measure the CA instead of adhesives as in this research. It is known, that after acetylation the chemistry is changed (Fodor et al. 2018), which might lower the CA for MUF or PRF on the acetylated surface compared to untreated specimens. The measured CA are typically phenomenological because they are not in an equilibrium state and are instead influenced by factors like substrate porosity and liquid penetration, wood swelling and MC, and any additional liquid contaminants that may be present on the wood surfaces. Additionally, the viscosity of the applied adhesives has an impact on the CA.

In this study, CA (Fig. 4) could not explain the TSS (Fig. 8). For instance, the TSS was high for specimens bonded with PRF and low for specimens bonded with MUF, despite the fact that CA of MUF and PRF were almost identical.