nach oben

Erschienen in:

01.09.2023 | ELECTRICAL AND MAGNETIC PROPERTIES

Structure and Magnetic Properties of Gd₂O₃ Nanoparticles Synthesized by Spark Discharge

verfasst von: A. V. Svalov, I. V. Beketov, A. D. Maksimov, A. I. Medvedev, D. S. Neznakhin, A. V. Arkhipov, G. V. Kurlyandskaya

Erschienen in: Physics of Metals and Metallography | Ausgabe 9/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Gadolinium oxide nanoparticles were synthesized by the electrophysical method of spark discharge. Their structural features and magnetic and magnetocaloric properties have been comparatively analyzed. According to X-ray diffraction analysis data, the synthesized Gd₂O₃ nanoparticles contain two crystallographic phases, cubic and monoclinic. The magnetic entropy change ΔS_M is determined from the data of magnetic isotherm measurements by the Maxwell relationship. The maximal ΔS_M at a magnetic field change amplitude of 2 T is approximately 17 J/(kg K) and observed at a temperature of 2.5 K.

Vorheriger Artikel Atomistic Simulation of Plastic Deformations in Hydrogen-Saturated Two-Phase Al/θ' Bicrystals

Nächster Artikel Magnetic Properties and Structure of the Fe63.5Mn10Cu1Nb3Si13.5B9 Alloy Nanocrystallized in the Presence of Tensile Stresses

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 340 Zeitschriften

aus folgenden Fachgebieten:

Bauwesen + Immobilien
Business IT + Informatik
Finance + Banking
Management + Führung
Marketing + Vertrieb
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

V. A. Pustovarov, E. S. Trofimova, Yu. A. Kuznetsova, and A. F. Zatsepin, “Upconversion luminescence of Gd₂O₃ nanocrystals doped with Er³⁺ and Yb³⁺ ions,” Tech. Phys. Lett. 44, 622–625 (2018). https://doi.org/10.1134/s106378501807026xCrossRef

J. Fang, P. Chandrasekharan, X.-L. Liu, Yo. Yang, Yu.‑B. Lv, Ch.-T. Yang, and J. Ding, “Manipulating the surface coating of ultra-small Gd₂O₃ nanoparticles for improved T1-weighted MR imaging,” Biomaterials 35, 1636–1642 (2014). https://doi.org/10.1016/j.biomaterials.2013.11.032CrossRef

R. Paul, T. Paramanik, K. Das, P. Sen, B. Satpati, and I. Das, “Magnetocaloric effect at cryogenic temperature in gadolinium oxide nanotubes,” J. Magn. Magn. Mater. 417, 182–188 (2016). https://doi.org/10.1016/j.jmmm.2016.05.057CrossRef

A. Zeleňáková, P. Hrubovčák, O. Kapusta, V. Zeleňák, and V. Franco, “Large magnetocaloric effect in fine Gd₂O₃ nanoparticles embedded in porous silica matrix,” Appl. Phys. Lett. 109, 122412–122415 (2016). https://doi.org/10.1063/1.4963267CrossRef

A. Zeleňáková, P. Hrubovčák, A. Berkutova, O. Šofranko, N. Kučerka, O. Ivankov, A. Kuklin, V. Girman, and V. Zeleňák, “Gadolinium-oxide nanoparticles for cryogenic magnetocaloric applications,” Sci. Rep. 12, 2282–2293 (2022). https://doi.org/10.1038/s41598-022-06132-8CrossRef

Z. W. Yang, S. Qin, J. Zhang, D. Lu, H. Zhao, C. Kang, H. Cui, Yo. Long, and Yu. Zeng, “Gadolinium oxyorthogermanate Gd₂GeO₅: An efficient solid refrigerant material for magnetic cryocoolers,” Mater. Today Phys. 27, 100810 (2022). https://doi.org/10.1016/j.mtphys.2022.100810CrossRef

S. Taskaev, V. Khovaylo, D. Karpenkov, I. Radulov, M. Ulyanov, D. Bataev, A. Dyakonov, D. Gunderov, K. Skokov, and O. Gutfleisch, “Plastically deformed Gd–X (X = Y, In, Zr, Ga, B) solid solutions for magnetocaloric regenerator of parallel plate geometry,” J. Alloys Compd. 754, 207–214 (2018). https://doi.org/10.1016/j.jallcom.2018.04.264CrossRef

V. V. Sokolovskiy, O. N. Miroshkina, V. D. Buchelnikov, and V. V. Marchenkov, “Magnetocaloric effect in metals and alloys,” Phys. Met. Metallogr. 123, 315–318 (2022). https://doi.org/10.1134/s0031918x2204010xCrossRef

D. Doblas, L. M. Moreno-Ramírez, V. Franco, A. Conde, A. V. Svalov, and G. V. Kurlyandskaya, “Nanostructuring as a procedure to control the field dependence of the magnetocaloric effect,” Mater. Des. 114, 214–219 (2017). https://doi.org/10.1016/j.matdes.2016.11.085CrossRef

10.

V. Franco and A. Conde, “Magnetic refrigerants with continuous phase transitions: Amorphous and nanostructured materials,” Scr. Mater. 67, 594–599 (2012). https://doi.org/10.1016/j.scriptamat.2012.05.004CrossRef

11.

L. Li and M. Yan, “Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration,” J. Alloys Compd. 823, 153810 (2020). https://doi.org/10.1016/j.jallcom.2020.153810CrossRef

12.

S. Hazarika, A. V. Morozkin, K. Gururaj, R. Nama, K. G. Pradeep, and R. Nirmala, “Magnetic and magnetocaloric properties of rare-earth substituted Gd₂O₃ nanorods,” AIP Adv. 12, 35208–35214 (2022). https://doi.org/10.1063/9.0000278CrossRef

13.

T. V. Pfeiffer, J. Feng, and A. Schmidt-Ott, “New developments in spark production of nanoparticles,” Adv. Powder Technol. 25, 56–70 (2014). https://doi.org/10.1016/j.apt.2013.12.005CrossRef

14.

G. V. Kurlyandskaya, D. S. Portnov, I. V. Beketov, A. Larrañaga, A. P. Safronov, I. Orue, A. I. Medvedev, A. A. Chlenova, M. B. Sanchez-Ilarduya, A. Martinez-Amesti, and A. V. Svalov, “Nanostructured materials for magnetic biosensing,” Biochim. Biophys. Acta (BBA) Gen. Subj. 1861, 1494–1506 (2017). https://doi.org/10.1016/j.bbagen.2016.12.003CrossRef

15.

I. V. Beketov, A. P. Safronov, A. I. Medvedev, J. Alonso, G. V. Kurlyandskaya, and S. M. Bhagat, “Iron oxide nanoparticles fabricated by electric explosion of wire: Focus on magnetic nanofluids,” AIP Adv. 2, 22154–22178 (2012). https://doi.org/10.1063/1.4730405CrossRef

16.

S. Hazarika, P. Behera, D. Mohanta, and R. Nirmala, “Magnetocaloric effect of Gd₂O₃ nanorods with 5% Eu-substitution,” Appl. Surf. Sci. 491, 779–783 (2019). https://doi.org/10.1016/j.apsusc.2019.05.266CrossRef

17.

B. Babić-Stojić, V. Jokanović, D. Milivojević, M. Požek, Z. Jagličić, D. Makovec, K. Arsikin, and V. Paunović, “Gd₂O₃ nanoparticles stabilized by hydrothermally modified dextrose for positive contrast magnetic resonance imaging,” J. Magn. Magn. Mater. 403, 118–126 (2016). https://doi.org/10.1016/j.jmmm.2015.11.075CrossRef

18.

A. E. Miller, F. J. Jelinek, K. A. Gschneidner, and B. C. Gerstein, “Low-temperature magnetic behavior of several oxides of gadolinium,” J. Chem. Phys. 55, 2647–2648 (1971). https://doi.org/10.1063/1.1676474CrossRef

19.

A. V. Svalov, V. O. Vas’kovskiy, and G. V. Kurlyandskaya, “Influence of the size and structural factors on the magnetism of multilayer films based on 3d and 4f metals,” Phys. Met. Metallogr. 118, 1263–1299 (2017). https://doi.org/10.1134/s0031918x17130026CrossRef

20.

K. Trepka and Ye. Tao, “Magnetic characterization of rare-earth oxide nanoparticles,” Appl. Phys. Lett. 117, 122410–122415 (2020). https://doi.org/10.1063/5.0023466CrossRef

21.

J.-H. Jia, Ya-J. Ke, X.-X. Zhang, J.-F. Wang, L. Su, Ya.-D. Wu, and Zh.-C. Xia, “Giant magnetocaloric effect in the antiferromagnet GdScO₃ single crystal,” J. Alloys Compd. 803, 992–997 (2019). https://doi.org/10.1016/j.jallcom.2019.06.361CrossRef

22.

S. Taskaev, K. Skokov, D. Karpenkov, V. Khovaylo, M. Ulyanov, D. Bataev, A. Dyakonov, A. Fazlitdinova, and O. Gutfleisch, “The effect of plastic deformation on magnetic and magnetocaloric properties of Gd–B alloys,” J. Magn. Magn. Mater. 442, 360–363 (2017). https://doi.org/10.1016/j.jmmm.2017.06.077CrossRef

23.

A. P. Kamantsev, V. V. Koledov, V. G. Shavrov, L. N. Butvina, A. V. Golovchan, V. I. Val’kov, B. M. Todris, and S. V. Taskaev, “Magnetocaloric effect and magnetization of gadolinium in quasi-stationary and pulsed magnetic fields up to 40 kOe,” Phys. Met. Metallogr. 123, 419–423 (2022). https://doi.org/10.1134/s0031918x22040068CrossRef

Titel: Structure and Magnetic Properties of Gd2O3 Nanoparticles Synthesized by Spark Discharge
verfasst von: A. V. Svalov
I. V. Beketov
A. D. Maksimov
A. I. Medvedev
D. S. Neznakhin
A. V. Arkhipov
G. V. Kurlyandskaya
Publikationsdatum: 01.09.2023
Verlag: Pleiades Publishing
Erschienen in: Physics of Metals and Metallography / Ausgabe 9/2023
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI: https://doi.org/10.1134/S0031918X23601348

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Wirtschaft"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 9/2023

Analysis of Suppression Conditions of Fe40Ni40P14B6 Melt Crystallization

The Decomposition of the Metastable Beta Phase in High-Strength Titanium Alloys VST5553, Ti–10V–2Fe–3Al, and BETA-21S

Magnetic Properties and Structure of the Fe63.5Mn10Cu1Nb3Si13.5B9 Alloy Nanocrystallized in the Presence of Tensile Stresses

Modeling of the Atomic Structure in the Vicinity of Spherical Voids in Aluminum and the Calculation of Anisotropy of the Void Growth Rate

Atomistic Simulation of Plastic Deformations in Hydrogen-Saturated Two-Phase Al/θ' Bicrystals

Effect of Ni on the Contributions of Superplastic Deformation Mechanisms in an Al–Zn–Mg–Cr Alloy